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Why can cotton clothes keep a crease after being folded?

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Answer: Folding lets molecular connections settle into a new arrangement

Folding breaks the fibers into shorter pieces along the fold — An ordinary crease does not require cotton fibers to snap. The fibers can remain intact while their internal molecular connections rearrange, which is why ironing can remove many creases without repairing broken threads.

Folding permanently removes air from the cotton fibers — Lost air does not lock cotton into a crease. The lasting shape reflects changes within and between the bent fibers; adding air back does not smooth the fold.

Folding lets molecular connections settle into a new arrangement ✓ — Cotton’s cellulose chains can shift when the fabric bends, and hydrogen bonds can reform in the changed arrangement. Moisture helps those connections rearrange, so a fold can persist after the pressure is removed. Heat and moisture during ironing help the chains move again as the fabric is smoothed.

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