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Why can black clothes look slimmer but feel hotter in sunlight?

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Answer: Absorbed light becomes heat

Absorbed light becomes heat ✓ — Black fabric absorbs much of the visible light falling on it, and that energy warms the cloth. Darker clothing can also make a wearer look slightly slimmer, a separate effect of how we judge shapes at different brightnesses. Neither effect is absolute: fit matters for appearance, and fabric and ventilation matter for how hot clothing feels.

Black traps extra air — Black dye does not by itself make a fabric trap more air. Air trapping depends on the weave, thickness and fit of a garment, so a loose black shirt need not feel hotter than a tight pale one. With those factors held similar, absorbing more sunlight is what can make the black fabric warmer.

Reflected light heats the cloth — Reflected light leaves the fabric rather than depositing its energy in it. Light that is absorbed can warm the cloth, so two otherwise similar fabrics may heat differently in sunlight. The slight slimming effect of dark clothing concerns visual perception, not extra heat produced by reflection.

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