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Why can a refrigerated chocolate bar turn grainy and pale after it is brought back into a room?

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Answer: Condensation drives sugar bloom

Cold destroys cocoa flavorThis overstates a flavor issue and misses the surface chemistry. Refrigeration can matter because moisture condenses when chocolate warms, not because cold directly destroys cocoa. The payoff is practical: the danger is often the wet transition, not the cold moment alone.

Condensation drives sugar bloomCorrect. Moisture or condensation can dissolve surface sugar; when the water evaporates, sugar recrystallizes as a pale, gritty layer. This is sugar bloom, not fat bloom. The useful distinction is that one white haze begins with water, while another begins with cocoa-butter movement.

Milk solids separate outThis invents a separation mechanism not cited here. The sources discuss sugar dissolving and recrystallizing under humidity, plus fat bloom from oil and temperature effects. Milk components can affect fat crystallization, but grainy sugar bloom is about water and sugar.

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